On the mechanical,thermophysical and dielectric properties of Nextel™ 440 fiber reinforced nitride matrix (N440/Nitride) composites

The Nextel? 440 fiber reinforced nitride matrix (N440/Nitride) composites were fabricated by precursor infiltration and pyrolysis (PIP) route. The results demonstrated that the original N440 fiber had a phase composition of amorphous SiO₂ and γ-Al₂O₃. Its single filament tensile strength was 3.03 GPa (at room temperature), while it dropped to 72.6% and 35.1% at 1200 °C and 1400 °C, respectively. The phase content of N440/Ntride composites was mainly γ-Al₂O₃ and amorphous BN, as well as mullite phase (formed at > 1100 °C). The composites owned a flexural strength up to 76.0 MPa at room temperature. The stair-stepping decrease in the load-displacement curve and fiber pull-outs in the fracture surface indicated a good fiber/matrix interface and toughness. By heating at 1400 °C, the composites still possessed 67.4% of original bending strength. It was found that the high temperatures caused strong fiber-matrix bonding and severe fiber degradation. The specific heat, CTE and thermal conductivity of the composites were 0.325–0.586 J g^?1 K^?1, (3.2–4.0) × 10^?6 K^?1 and 0.78–3.47 W m^?1 K^?1, respectively. The composites possessed a dielectric constant of 4.25–4.35 and loss tangent of 0.004–0.01 at 8–12 GHz. The good overall performances enabled the N440/Nitride composites advanced high-temperature wave-transparent applications.     

Synergistic effects of stochastic loading stress and time on stress-rupture damage evolution and lifetime of fiber-reinforced ceramic-matrix composites at intermediate temperatures

In this paper, the synergistic effects of the stochastic loading stress and time interval on the stress-rupture damage evolution and lifetime of fiber-reinforced ceramic-matrix composites (CMCs) at intermediate temperatures are investigated. The relationships between the stochastic loading stress and stochastic time interval, internal damage evolution, macro strain, broken fiber fraction, and stress-rupture lifetime of fiber-reinforced CMCs are established. The effects of the stochastic loading stress and stochastic time interval, constituent properties, damage condition, and environment temperature on the stress-rupture time, strain evolution, and internal damage of SiC/SiC composite under stress-rupture loading are discussed. The experimental stress-rupture behavior of SiC/SiC composite under constant and stochastic loading condition are predicted. The stress-rupture lifetime decreases with increase of stochastic stress level, stochastic time interval, and environmental temperature, and increases with the fiber volume and interfacial shear stress in the slip region.     

The characterisation of geosynthetic interface friction by means of the inclined plane test

The paper focuses on the evaluation of the shear strength in conditions of low normal stress of various geosynthetic-geosynthetic interfaces, which are typical of landfill cover systems, by means of the inclined plane test, with the aim of studying the friction mobilisation in relation to various kinematic behaviours. The results of three different methods to evaluate the angle of friction were analysed, together with the sensitivity of the interfaces in relation to the wear effect and the influence of the state of hydration. The results showed very different responses of the interfaces to the shear stress, which involved three main types of sliding mechanisms, referred to as sudden, gradual and uneven sliding. Another outcome observed was that the shear strength of geosynthetic-geosynthetic interfaces cannot always be properly characterised following the procedure proposed by the European standard for soil-geosynthetic interfaces (EN ISO 12957–2), since the actual mobilised kinematic behaviour should be taken into consideration. In this regard, the paper provides some hints on the choice of the more representative parameter of friction for each type of sliding. A particular focus was given to the case of gradual sliding interfaces, for which the static friction is difficult to detect due to the very slow movements; for practical purposes, the design friction of these interfaces should be evaluated by using an adequate safety factor with respect to the friction evaluated at 1 mm of displacement.     

Influence of tensile pre-fatigue stress on residual strength of SiC/(PyC/SiC)2/SiC minicomposites

The tensile-tension fatigue behavior of minicomposite SiC/(PyC/SiC)2/SiC at room temperature was studied, and the residual mechanical properties of specimens were tested after 10⁶ pre-fatigue cycles under different levels of stress. The results show that the residual strength first increases owing to the release of stress concentration and then decreases owing to excessive fiber wear. In addition, it is worth noting that the tensile curve of pre-fatigue specimens deflects twice; the first occurrence correlates with matrix crack reopening, and the second occurs when the uniaxial tensile load exceeds the pre-fatigue stress, and the degree of deflection also gradually decreases or almost disappears.     

Construction of quantum-scale catalytic regions on anatase TiO2 nanoparticles by loading TiO2 quantum dots for the photocatalytic degradation of VOCs

We constructed quantum-scale catalytic regions on the surfaces of TiO₂ nanoparticles by loading TiO₂ quantum dots (QDs) with a two-step method. The removal rate and mineralization efficiency of toluene were measured and then used in evaluating the oxidation performance of the prepared samples. A home-built atmospheric surface photovoltage spectrometer and X-ray photoelectron spectrometer were used in analyzing band alignment across the interface between TiO₂ QD and TiO₂ particle and the transfer of charge carriers at the surface. Results showed that an upward band bending formed from the TiO₂ particle to the TiO₂ QD and promoted the accumulation of holes at the QD side. Moreover, the QD and surrounding substrate TiO₂ formed a quantum-scale catalytic region, improving the reaction probability of electron-hole pairs and corresponding intermediates. The mineralization efficiency of toluene in QD-loaded TiO₂ reached 95.8%. The synthetic method is green and simple, showing potential in scale production and industrial application.     

SCTF nanosheets@sulfonated poly (p-phenylene-co-aryl ether ketone) composite proton exchange membranes for passive direct methanol fuel cells

The development of a simple and efficient methanol-resistant membrane strategy is of great significance for improvement of the performance of fuel cells, making it an attractive and challenging topic. In this work, sulfonated covalent triazine framework (SCTF) nanosheets are prepared by a micro-interface method and post-sulfonation, which show excellent dispersion in polar solutions, such as water and N, N-Dimethylacetamide (DMAc). Then a series of composite proton exchange membranes (SCTF-x@SPP-co-PAEKs) are prepared by blending these SCTF nanosheets with sulfonated micro-block copolymers (SPP-co-PAEKs) resin. The results show that the appropriate addition of SCTF can significantly improve the proton conductivity (PC), methanol resistance and fuel cell performance of the prepared composite membrane, which can be attributed to the good interfacial compatibility between the SCTF nanosheets and the sulfonated micro-block copolymer matrix. The passive direct methanol fuel cells (DMFCs) with SCTF-x@SPP-3 membrane exhibit power density in the range of 28.0–33.3 mW cm⁻² at 25 °C, which is superior to the related values of the pristine membrane and the commercial Nafion® series membranes.     

Effects of glass-ceramic spray deposition manipulation on the surface characteristics of zirconia dental restorations

A novel glass-ceramic spray deposition (GCSD) method was developed to modify the yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) surface and to enhance the bond strength between Y-TZP and resin cement. Five different experimental groups were characterized, non-treatment (NT), airborne particle abrasion (AB), GCSD without etching (GS), GCSD with 5% HF etching (GSE5), and GCSD with 9.5% HF etching (GSE9), to determine the optimal method for improving the bond strength. Scanning electron microscopy and an argon ion milling system were used to investigate the surface and cross-sectional microstructures. The changes in the surface characteristics of Y-TZP were analyzed via contact angle analysis, atomic force microscopy, X-ray diffraction, and energy-dispersive X-ray spectrometry. The bond strengths were determined using shear bond strength test. The results revealed that GCSD could produce a dense and uniform lithium disilicate glass-ceramic coating layer and infiltrate the Y-TZP surface. This coating resulted in superior micromechanical interlocking and increased hydrophilicity, thereby enhancing the bond strength between Y-TZP and resin cement (P < 0.05). The study findings indicated that GCSD accompanied by 5% HF etching for 100 s is optimal for strengthening the Y-TZP/resin cement bond, thereby providing a novel solution for dental bonding systems.     

基于优化外卖配送服务的微信小程序界面设计

随着o2o商业模式及"互联网+"的发展,外卖服务融入到人们的日常生活中,给快节奏的都市生活带来便利。越来越多的外卖形式和种类的出现,使得人们对于外卖服务的要求也随之提高,用户更关注外卖的品质和体验。文章通过文献调研、问卷调查等方式,将数据与图表结合,分析用户在使用外卖时的需求。基于外卖存储站点、实时画面监督、餐盒回收功能、餐具数量细化、外卖时效转售等用户具体体验对小程序进行设计。通过对点餐平台内的功能进行升级及增加,并提出外卖储存点的概念,提高用户体验的同时让外卖服务为快节奏的城市生活带来更多可能。     

电磁制动下钢液射流及钢-渣界面波动行为的数值模拟

建立了描述全幅一段电磁制动作用下结晶器内钢液射流及钢-渣界面波动行为的数学模型,采用数值模拟方法研究了不同电磁参数对结晶器内钢液射流及其引起的钢-渣界面波动行为的影响,分析了磁感应强度及水平磁极与浸入式水口之间距离变化对结晶器内钢液射流行为和钢-渣界面波动行为的影响。结果表明,当全幅一段电磁制动稳恒磁场同时覆盖射流冲击区域、上返流和下返流区域时(D=20mm),电磁制动的施加可以有效控制钢液射流结构,降低上返流和下返流钢液流速,稳定钢-渣界面波动;当电磁制动水平磁极与浸入式水口垂直距离较远时(D=220mm),增大磁感应强度不能对结晶器内上返流区域钢液流速进行抑制,不利于钢-渣界面波动的稳定,增大卷渣发生几率。     

Effect of prehydration,permeant, and desiccation on GCL/Geomembrane interface transmissivity

A laboratory investigation was conducted on two different conventional GCLs (one with fine granular and another one with powdered bentonite) to explore the effect of prehydration and permeant fluid; GCL desiccation on the interface transmissivity, θ, between the interfaces of a 1.5 mm-thick high-density polyethylene (HDPE) geomembrane (GMB) and a GCL. The study also aimed to assess the self-healing capacity of desiccated GCLs for three different permeant solutions under a range of applied stresses (10–150 kPa). It was found that at stresses less than 70 kPa, θ was dominated by variability in the initial contact condition between the GMB-GCL interfaces. The effect of other factors was largely masked by the contact variability. At 100–150 kPa, the effects of initial variability were largely eliminated, but there was no notable effect of other factors on θ in the absence of desiccation. GCL desiccation increased θ by up to three orders of magnitude than an intact specimen at 10–100 kPa. Even at 150 kPa, desiccated specimens had a θ ≤ 8.0 × 10⁻⁹ m²/s for all specimens tested. The chemical composition of the permeant solutions, crack width, and nature of bentonite could play an important role in healing the cracks of desiccated GCLs.